Aug 21, 2008· 2.2. Synthesis of the complexes2.2.1.General procedure for the preparation of cis-[Pt(L n) 2 Cl 2] (1–3), L n = L 1 –L 3. An appropriate ligand (1 mmol) was dissolved in chloroform (15 mL) and added to a mixture of PtCl 2 (0.09. g, 0.5 mmol) in the same solvent (10 mL).. The reaction mixture was stirred at −18 °C for 15 days.Obtained yellow or light orange solutions …
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Sep 15, 2021· Here, a series of Pt–Ln/C (Ln = La, Ce, Pr, Nd) nanoalloy catalysts were synthesized to improve the electroactivity towards methanol oxidation and suppress the CO poisoning effect of Pt. DFT calculations have unravelled the different electronic structures of different Pt 5 Ln samples, in which the optimal d–f coupling in Pt 5 Ce leads to ...
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